3783-38-8
- Product Name：4-(methoxycarbonyl)pyridine 1-oxide
- Molecular Formula：C7H7 N O3
- Purity：99%
- Molecular Weight：153.137
Product Details
pd_meltingpoint:116.5-118.5 °C(Solv: ethyl acetate (141-78-6))
Purity:99%
Reliable Quality 4-(methoxycarbonyl)pyridine 1-oxide 3783-38-8 Hot Sale with Chinese Manufacturer
- Molecular Formula:C7H7 N O3
- Molecular Weight:153.137
- Vapor Pressure:8.59E-05mmHg at 25°C
- Melting Point:116.5-118.5 °C(Solv: ethyl acetate (141-78-6))
- Boiling Point:340.5°Cat760mmHg
- PKA:-0.41±0.10(Predicted)
- Flash Point:159.7°C
- PSA：51.76000
- Density:1.2g/cm3
- LogP:0.90170
METHYLISONICOTINATE-N-OXIDE(Cas 3783-38-8) Usage
InChI:InChI=1/C7H7NO3/c1-11-7(9)6-2-4-8(10)5-3-6/h2-5H,1H3
3783-38-8 Relevant articles
Controlling the optical and catalytic properties of artificial metalloenzyme photocatalysts using chemogenetic engineering
Gu, Yifan,Lewis, Jared C.,Liu, Bingqing,Sahoo, Dipankar,Zubi, Yasmine S.
, p. 1459 - 1468 (2022/02/14)
Visible light photocatalysis enables a b...
A Photosensitizer-Free Radical Cascade for Synthesizing CF3-Containing Polycyclic Quinazolinones with Visible Light
Hu, Qiang,Yu, Wan-Lei,Luo, Yong-Chun,Hu, Xiu-Qin,Xu, Peng-Fei
supporting information, p. 1493 - 1501 (2022/02/07)
Herein, we report an efficient photoindu...
Visible-Light-Induced ortho-Selective Migration on Pyridyl Ring: Trifluoromethylative Pyridylation of Unactivated Alkenes
Jeon, Jinwon,He, Yu-Tao,Shin, Sanghoon,Hong, Sungwoo
supporting information, p. 281 - 285 (2019/11/26)
The photocatalyzed ortho-selective migra...
Photoredox generation of the trifluoromethyl radical from borate complexes: Via single electron reduction
Smirnov, Vladimir O.,Maslov, Anton S.,Kokorekin, Vladimir A.,Korlyukov, Alexander A.,Dilman, Alexander D.
supporting information, p. 2236 - 2239 (2018/03/06)
A method for the generation of the CF3 r...
3783-38-8 Process route
-
-
2459-09-8
4-pyridinecarboxylic acid, methyl ester
-
-
3783-38-8
methyl isonicotinate N-oxide
| Conditions | Yield |
|---|---|
|
4-pyridinecarboxylic acid, methyl ester;
With
dihydrogen peroxide; methyltrioxorhenium(VII);
In
dichloromethane; water;
at 20 ℃;
for 18h;
With
manganese(IV) oxide;
In
dichloromethane;
at 20 ℃;
for 2h;
|
99% |
|
With
bis-trimethylsilanyl peroxide; per-rhenic acid;
In
dichloromethane; water;
at 24 ℃;
for 6h;
|
98% |
|
With
dihydrogen peroxide; methyltrioxorhenium(VII);
In
dichloromethane; water;
at 24 ℃;
for 17h;
|
98% |
|
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 20 ℃;
for 24h;
Inert atmosphere;
|
97% |
|
With
dihydrogen peroxide; methyltrioxorhenium(VII);
In
dichloromethane; water;
at 20 ℃;
Inert atmosphere;
|
95% |
|
With
dihydrogen peroxide; acetic acid;
at 70 ℃;
Solvent;
|
95.2% |
|
With
dihydrogen peroxide;
In
acetic acid;
at 70 ℃;
Solvent;
|
95.2% |
|
With
dihydrogen peroxide; methyltrioxorhenium(VII);
In
dichloromethane;
at 24 ℃;
for 12h;
Inert atmosphere;
|
93% |
|
With
dihydrogen peroxide; acetic acid;
at 70 ℃;
|
92% |
|
4-pyridinecarboxylic acid, methyl ester;
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
for 6h;
Inert atmosphere;
Reflux;
With
potassium carbonate;
In
dichloromethane;
Inert atmosphere;
|
91% |
|
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
|
78% |
|
With
dihydrogen peroxide; acetic acid;
|
70% |
|
With
dihydrogen peroxide;
In
water; acetic acid;
|
65% |
|
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 20 ℃;
for 3h;
Sealed tube;
|
46% |
|
With
Perbenzoic acid;
In
1,4-dioxane; water;
at 20 ℃;
Thermodynamic data;
Kinetics;
Mechanism;
other temp. (25, 30 deg C); ΔS(excit.);
|
|
|
With
dihydrogen peroxide; acetic acid;
|
|
|
4-pyridinecarboxylic acid, methyl ester;
With
dihydrogen peroxide;
methyltrioxorhenium(VII);
In
dichloromethane;
at 20 ℃;
manganese(IV) oxide;
In
dichloromethane;
at 20 ℃;
for 1h;
|
|
|
With
3-chloro-benzenecarboperoxoic acid;
In
acetonitrile;
at 95 ℃;
under 6000.6 Torr;
Flow reactor;
|
|
|
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 20 ℃;
for 18h;
|
|
|
4-pyridinecarboxylic acid, methyl ester;
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 0 - 20 ℃;
for 6h;
With
triphenylphosphine;
In
dichloromethane;
at 20 ℃;
for 4h;
|
-
-
67-56-1
methanol
-
-
13602-12-5
Isonicotinic acid N-oxide
-
-
3783-38-8
methyl isonicotinate N-oxide
| Conditions | Yield |
|---|---|
|
With
diazomethyl-trimethyl-silane;
In
hexane;
at 0 ℃;
for 1h;
|
97% |
|
With
thionyl chloride;
at 20 ℃;
for 2h;
|
72% |
|
With
sulfuric acid;
In
toluene;
Reflux;
Dean-Stark;
|
45% |
3783-38-8 Upstream products
-
2459-09-8
4-pyridinecarboxylic acid, methyl ester
-
67-56-1
methanol
-
13602-12-5
Isonicotinic acid N-oxide
-
16357-59-8
N-ethoxycarbonyl-2-ethoxy-1,2-dihydroquinoline
3783-38-8 Downstream products
-
58481-11-1
methyl 2-chloroisonicotinate
-
89937-77-9
methyl 2-hydroxypyridine-4-carboxylate
-
2459-09-8
4-pyridinecarboxylic acid, methyl ester
-
94413-64-6
2-Cyano-4-carbomethoxypyridine
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